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PhysicsISC Class 11 · Chapter 10

Thermal Properties of Matter ISC Class 11: Notes and Numericals

Updated 15 October 2026 · Fact-checked

Thermal Properties of Matter is Chapter 10 of ISC Class 11 Physics. It covers temperature scales and absolute temperature, thermal expansion of solids, liquids and gases, the anomalous expansion of water, specific heat and calorimetry, latent heat, conduction and thermal conductivity, convection, blackbody radiation with Stefan's and Wien's laws, and Newton's law of cooling.

What Thermal Properties of Matter is about

Heat is energy transferred because of a temperature difference; temperature measures how hot a body is and decides the direction of heat flow. Temperature scales are related by . The ideal gas equation pV = nRT leads to the absolute (kelvin) scale, whose zero is where an ideal gas would exert no pressure.

Expansion. Most substances expand when heated: linear expansion , with area and volume coefficients β = 2α and γ = 3α for solids. Liquids show apparent and real expansion; for an ideal gas at constant pressure γ = 1/T. Water is anomalous: it contracts from 0 °C to 4 °C and is densest at 4 °C, so lakes freeze from the top and life survives below.

Calorimetry. Heat Q = mcΔT raises temperature (c is the specific heat capacity); Q = mL changes state at constant temperature (L is the specific latent heat). In a mixture, heat lost = heat gained.

Transfer of heat. Conduction: in the steady state, heat current , where K is the coefficient of thermal conductivity, found for a good conductor by Searle's experiment (Lee's disc is not required). Convection carries heat by the bulk movement of fluid (sea breezes, room heaters). Radiation needs no medium. A blackbody (approximated by a cavity with a small hole) absorbs all radiation and emits the most possible: Stefan-Boltzmann law I = σT⁴ (or eσT⁴ with emissivity e), and Wien's law = constant, from the spectral radiancy curve. Newton's law of cooling: for small temperature differences, the rate of cooling is proportional to the excess temperature over the surroundings. Deductions from Stefan's law are not required.

Weightage: Thermal Properties of Matter belongs to unit 8 of the ISC Class XI Physics syllabus. CISCE weights units 7-9 together (Properties of Bulk Matter; Heat and Thermodynamics; Behaviour of Perfect Gases and Kinetic Theory of Gases) at 20 of the 70 marks in Paper I (Theory). Class XI is examined by the school, so your school sets the paper within this weightage.Source: CISCE ISC Physics syllabus, examination year 2028, Class XI unit weightage

Key concepts

Heat, temperature and temperature scales

Heat is energy in transit from a hotter to a colder body (joule). Temperature is the property that decides which way heat flows; two bodies in thermal equilibrium have the same temperature. A temperature scale needs two fixed points: the ice point and the steam point at standard pressure. Celsius: 0 and 100; Fahrenheit: 32 and 212; Kelvin: 273.15 and 373.15. Conversion: . A temperature difference of 1 °C equals 1 K and 1.8 °F. The Celsius and Fahrenheit scales agree at −40°.

Worked example

Normal body temperature is 98.6 °F. Express it in °C and K. At what temperature do the Celsius and Fahrenheit scales give the same reading?

Try it first, then show the solutionSolution
  1. C = (98.6 − 32) × 100/180 = 37 °C; K = 37 + 273.15 = 310.15 K
  2. Put C = F = x: x/100 = (x − 32)/180, so 180x = 100x − 3200 and x = −40

Answer: 37 °C, 310.15 K; −40°

Ideal gas equation and absolute temperature

Real gases at low pressure obey Boyle's law (pV constant at fixed T) and Charles's law (V/T constant at fixed p), which combine into the ideal gas equation: pV = nRT, with R = 8.31 J mol⁻¹ K⁻¹. In a constant-volume gas thermometer, pressure varies linearly with temperature; extending the line to zero pressure gives the same temperature, −273.15 °C, for every gas. This is absolute zero, the zero of the absolute (kelvin) scale: T = t + 273.15. Temperatures in gas laws must always be in kelvin.

Worked example

A car tyre has a pressure of 2.0 × 10⁵ Pa at 27 °C. After a long drive its temperature is 47 °C. Find the new pressure, assuming the volume stays constant.

Try it first, then show the solutionSolution
  1. p₂ = 2.0 × 10⁵ × 320/300 = 2.13 × 10⁵ Pa

Answer: About Pa (use kelvin, not 47/27)

Thermal expansion of solids

On heating, the atoms vibrate with larger amplitude about positions that drift slightly apart, so solids expand. Linear expansion: , where α is the coefficient of linear expansion (K⁻¹). Area expansion: ; volume expansion: . For an isotropic solid β = 2α and γ = 3α. Examples: gaps in railway tracks and expansion joints in bridges; the bimetallic strip (two metals of different α riveted together bend on heating, used in thermostats); fitting an iron tyre on a wheel by heating it. If a rod is clamped so that it cannot expand, a thermal stress develops.

Worked example

Steel rails 25 m long are laid at 10 °C. What gap must be left between them if the temperature can reach 50 °C? (α = 1.2 × 10⁻⁵ K⁻¹)

Try it first, then show the solutionSolution
  1. ΔL = αLΔT = 1.2 × 10⁻⁵ × 25 × 40
  2. ΔL = 0.012 m

Answer: At least 12 mm

Expansion of liquids and gases; anomalous expansion of water

A liquid has no shape of its own, so only volume expansion matters. The container also expands, so the apparent expansion seen is less than the real expansion: . Gases expand far more. For an ideal gas at constant pressure, V ∝ T, so ; at 0 °C, γ = 1/273 K⁻¹. Anomalous expansion of water: from 0 °C to 4 °C water contracts on heating; above 4 °C it expands normally. So water is densest at 4 °C. In winter, as surface water cools to 4 °C it sinks; below 4 °C the colder, lighter water stays on top and freezes; ice, a poor conductor, insulates the water below, which stays at about 4 °C at the bottom, so aquatic life survives.

Worked example

A glass flask of volume 500 cm³ is filled to the brim with mercury at 20 °C. How much mercury overflows when both are heated to 100 °C? (γ of mercury = 1.8 × 10⁻⁴ K⁻¹, γ of glass = 2.7 × 10⁻⁵ K⁻¹)

Try it first, then show the solutionSolution
  1. Overflow = V(γ_Hg − γ_glass)ΔT
  2. = 500 × (1.8 × 10⁻⁴ − 0.27 × 10⁻⁴) × 80 = 500 × 1.53 × 10⁻⁴ × 80
  3. = 6.12 cm³

Answer: About 6.1 cm³ (the apparent expansion)

Specific heat capacity and calorimetry

The heat needed to raise the temperature of mass m by ΔT is Q = mcΔT, where c is the specific heat capacity: the heat needed to raise the temperature of unit mass by 1 K (J kg⁻¹ K⁻¹). Water has an unusually high c, 4200 J kg⁻¹ K⁻¹, so it warms and cools slowly (coastal climates are mild; water is a good coolant). Heat capacity (thermal capacity) of a body = mc (J K⁻¹). Molar specific heat = heat per mole per kelvin. Principle of calorimetry: when hot and cold bodies are mixed in an insulated container, heat lost by the hot bodies = heat gained by the cold ones (conservation of energy). The calorimeter itself (usually copper) also absorbs heat; include its heat capacity unless told to neglect it.

Worked example

200 g of copper at 100 °C is dropped into 300 g of water at 20 °C. Find the final temperature, neglecting the calorimeter. (c of copper 390, of water 4200 J kg⁻¹ K⁻¹)

Try it first, then show the solutionSolution
  1. Heat lost by copper = heat gained by water: 0.2 × 390 × (100 − T) = 0.3 × 4200 × (T − 20)
  2. 78(100 − T) = 1260(T − 20), so 1338T = 33 000
  3. T = 24.7 °C

Answer: About 24.7 °C

Change of state and latent heat

During melting, boiling and their reverses, heat is absorbed or released at constant temperature: it changes the molecular arrangement (potential energy), not the average kinetic energy. Specific latent heat L is the heat needed to change unit mass from one state to another without change of temperature: Q = mL. For water, (fusion) = 3.36 × 10⁵ J kg⁻¹ and (vaporisation) = 2.26 × 10⁶ J kg⁻¹. A heating curve (temperature against heat supplied) has sloping parts (Q = mcΔT) and flat parts (Q = mL). The melting point of ice falls with increased pressure (regelation: a loaded wire passes through a block of ice, which refreezes behind it), and the boiling point rises with pressure (pressure cooker). Steam burns are worse than boiling-water burns because steam gives up its latent heat as it condenses.

Worked example

Find the heat needed to turn 100 g of ice at −10 °C into steam at 100 °C. (c_ice = 2100, c_water = 4200 J kg⁻¹ K⁻¹; L_f = 3.36 × 10⁵, L_v = 2.26 × 10⁶ J kg⁻¹)

Try it first, then show the solutionSolution
  1. Ice −10 → 0 °C: 0.1 × 2100 × 10 = 2100 J; melting: 0.1 × 3.36 × 10⁵ = 33 600 J
  2. Water 0 → 100 °C: 0.1 × 4200 × 100 = 42 000 J; boiling: 0.1 × 2.26 × 10⁶ = 226 000 J
  3. Total = 303 700 J

Answer: About J (three-quarters of it is the latent heat of vaporisation)

Conduction: steady state, temperature gradient and thermal conductivity

In conduction, heat passes through a material from particle to particle without the material moving (free electrons carry most of it in metals). When one end of a rod is heated, its temperatures first rise everywhere (variable state); eventually each point reaches a constant temperature: the steady state, in which no heat is absorbed and the heat entering each cross-section per second equals that leaving. The temperature gradient is the fall of temperature per unit length, . In the steady state the heat current is , where K is the coefficient of thermal conductivity (W m⁻¹ K⁻¹). Metals have high K (copper ≈ 385), insulators low K (air ≈ 0.025). Thermal resistance R = L/(KA); slabs in series add resistances, so for two slabs of equal thickness the junction temperature is .

Worked example

(a) A copper rod 0.5 m long with a cross-section of 1 cm² has its ends at 100 °C and 0 °C. Find the heat current. (K = 385 W m⁻¹ K⁻¹) (b) Two slabs of equal thickness and area, with K₁ = 2K₂, are joined face to face; the outer faces are at 100 °C and 0 °C. Find the junction temperature.

Try it first, then show the solutionSolution
  1. (a) H = 385 × 10⁻⁴ × 100/0.5 = 7.7 W
  2. (b) Equal heat current: K₁(100 − θ) = K₂(θ − 0) → 2(100 − θ) = θ
  3. θ = 66.7 °C

Answer: (a) 7.7 W (b) 66.7 °C (nearer the hot face, across the better conductor)

Searle's experiment for the thermal conductivity of a good conductor

A thick, well-lagged metal bar (e.g. copper) is heated at one end by steam; the other end is cooled by water flowing steadily through a copper coil wound round it. Two thermometers in holes a distance d apart along the bar read θ₁ and θ₂; two more read the inflow and outflow water temperatures θ₃ and θ₄. When all four are steady (steady state), the heat conducted through the bar per second equals the heat carried away by the water: , where m is the mass of water collected in time t. Lagging prevents heat loss from the sides so that the heat flow is parallel to the axis. A thick bar (large A) and a long gap d make the temperature difference large enough to measure. (Lee's disc method for poor conductors is not required.)

Worked example

In Searle's experiment, the bar has a radius of 2 cm, the thermometers 10 cm apart read a difference of 10 K, and water flows at 2.3 g per second, rising 5 K in temperature. Find K. (c of water = 4200 J kg⁻¹ K⁻¹)

Try it first, then show the solutionSolution
  1. Heat carried by water per second = 0.0023 × 4200 × 5 = 48.3 W
  2. A = π(0.02)² = 1.26 × 10⁻³ m²

Answer: About 384 W m⁻¹ K⁻¹ (copper)

Convection and radiation: blackbody, Stefan's law and Wien's law

Convection transfers heat by the actual movement of the heated fluid: warm fluid becomes less dense and rises, cooler fluid sinks (natural convection: sea and land breezes, room heaters near the floor); with a fan or pump it is forced convection. Radiation transfers energy as electromagnetic waves, needs no medium and travels at the speed of light (sunlight). A perfect blackbody absorbs all radiation falling on it; a cavity with a small hole is the best approximation, and its cavity radiation depends only on its temperature. Emissivity e (0 to 1) compares a surface with a blackbody; good absorbers are good emitters. Stefan-Boltzmann law: the energy radiated per second per unit area is I = σT⁴ for a blackbody (σ = 5.67 × 10⁻⁸ W m⁻² K⁻⁴), eσT⁴ for other bodies; net loss to surroundings at T₀ is eσA(T⁴ − T₀⁴). Spectral radiancy R(λ) plotted against λ gives a hump-shaped curve for each temperature; a hotter body gives a higher curve (more total energy, the area) with its peak at a shorter wavelength. Wien's displacement law: , with b ≈ 2.9 × 10⁻³ m K. (Qualitative ideas; deductions from Stefan's law are not required.)

Worked example

The Sun's radiation peaks at about 500 nm. Estimate its surface temperature. At what wavelength does the human body (310 K) radiate most?

Try it first, then show the solutionSolution
  1. Body:

Answer: About 5800 K; about 9.4 μm (infrared, used by thermal cameras)

Newton's law of cooling

Newton's law of cooling: the rate of loss of heat of a body is directly proportional to the difference in temperature between the body and its surroundings, provided the difference is small: , so . A cooling curve (temperature against time) falls steeply at first and then more slowly as T approaches T₀. In problems over a range of temperatures, use the average form: . The law can be seen as a small-difference form of the Stefan-Boltzmann result for radiation (with convection also contributing).

Worked example

A body cools from 80 °C to 60 °C in 10 minutes in a room at 20 °C. How long will it take to cool from 60 °C to 40 °C?

Try it first, then show the solutionSolution
  1. First interval: 20/10 = K(70 − 20), so K = 0.04 min⁻¹
  2. Second: 20/t = 0.04(50 − 20) = 1.2
  3. t = 16.7 min

Answer: About 16.7 minutes (it cools more slowly as it nears room temperature)

Physics in real life: Thermal Properties of Matter

Each concept, met in an everyday situation. Read the situation, try the problem, then check the solution. The one-line hook is what to remember.

Expansion joints in a bridge

Suppose a steel road bridge is 300 m long and its temperature ranges from −5 °C in winter to 45 °C in summer. (α = 1.2 × 10⁻⁵ K⁻¹)

By how much does its length change over the year?

Try it first, then show the solutionSolution
  1. ΔT = 50 K
  2. ΔL = αLΔT = 1.2 × 10⁻⁵ × 300 × 50 = 0.18 m

Answer: About 18 cm, which the expansion joints must absorb; without them the bridge would buckle or crack.

Memory hook: Long and hot means big growth.

Specific heat and an electric kettle

Imagine boiling 1 litre of water from 20 °C in a 2 kW kettle that delivers 80% of its energy to the water.

How long does it take to reach 100 °C?

Try it first, then show the solutionSolution
  1. Heat needed = mcΔT = 1 × 4200 × 80 = 336 000 J
  2. Useful power = 0.8 × 2000 = 1600 W; t = 336 000/1600 = 210 s

Answer: About 3.5 minutes.

Memory hook: Water's big c makes it slow to heat.

Cooling by sweating (latent heat)

Suppose a runner's body evaporates 0.5 kg of sweat in an hour, and the latent heat of vaporisation at skin temperature is about 2.4 × 10⁶ J kg⁻¹.

At what rate does evaporation remove heat?

Try it first, then show the solutionSolution
  1. Heat removed = mL = 0.5 × 2.4 × 10⁶ = 1.2 × 10⁶ J per hour
  2. Rate = 1.2 × 10⁶/3600 = 333 W

Answer: About 330 W, like switching off a small heater inside the body.

Memory hook: Evaporation steals latent heat.

Topics in this chapter

Thermal Properties of Matter formula sheet

Temperature scales
Equal at −40 for C and F.
Ideal gas equation
T in kelvin; R = 8.31 J mol⁻¹ K⁻¹.
Thermal expansion
Ideal gas at constant p: γ = 1/T.
Thermal stress
Rod prevented from expanding.
Heat and specific heat
Heat capacity = mc.
Latent heat
At constant temperature.
Heat conduction
Steady state; series resistances add.
Searle's method
Good conductors.
Stefan-Boltzmann law
σ = W m⁻² K⁻⁴.
Wien's displacement law
Hotter: peak at shorter λ.
Newton's law of cooling
Small temperature differences.

Thermal Properties of Matter: diagrams to practise

Practise each one on paper: draw it from the checklist, then tick off every label.

Searle's apparatus for thermal conductivity

Describing the determination of K of a good conductor.

Draw

  1. A thick metal bar, lagged with felt, with a steam chest round its left end (steam in, steam out).
  2. A copper coil round the right end with water entering (θ₃) and leaving (θ₄).
  3. Two thermometers in holes in the bar a distance d apart reading θ₁ and θ₂.

Label

  • steam chest
  • metal bar
  • lagging
  • θ₁
  • θ₂
  • d
  • water in (θ₃)
  • water out (θ₄)
  • copper coil

Watch out: Write 'steady state: all four thermometers constant' and the heat balance equation beside the figure.

Spectral radiancy of a blackbody at different temperatures

Explaining blackbody radiation and Wien's displacement law.

Draw

  1. Axes: spectral radiancy R(λ) on the y-axis and wavelength λ on the x-axis.
  2. Three hump-shaped curves for T₃ > T₂ > T₁, each starting near zero at small λ.
  3. Mark λ_max for each, shifting to the left as T rises; the hotter curve lies above at every wavelength.

Label

  • R(λ)
  • λ
  • T₁
  • T₂
  • T₃
  • λ_max
  • area = total power (σT⁴)

Watch out: Note that the curves never cross, and the area under each curve grows as T⁴.

Heating curve of water

Explaining latent heat and change of state.

Draw

  1. Axes: temperature on the y-axis and heat supplied (or time) on the x-axis.
  2. A rising line from −10 °C to 0 °C (ice), a flat line at 0 °C (melting), a rising line to 100 °C (water), a long flat line at 100 °C (boiling) and a rise for steam.
  3. Label each part with Q = mcΔT or Q = mL.

Label

  • ice
  • melting (0 °C)
  • water
  • boiling (100 °C)
  • steam
  • mcΔT
  • mL_f
  • mL_v

Watch out: Make the boiling plateau much longer than the melting one: L_v is about seven times L_f.

How the school exam asks Thermal Properties of Matter

The question patterns to expect, and the method that works for each.

Question typeHow it is askedMethod
Scales and gas lawsConvert temperatures; explain absolute zero; use pV = nRT with temperatures in kelvin.Use the ratio formula for scales; always add 273 before using gas laws.
ExpansionRail gaps, bridges, bimetallic strips, thermal stress, apparent expansion of liquids, anomalous expansion of water.ΔL = αLΔT; for liquids subtract the vessel's expansion; explain lake freezing step by step.
Calorimetry and latent heatMixtures, ice and water, steam, heating curves.Heat lost = heat gained; first check whether all the ice melts.
ConductionHeat current through rods and walls; composite slabs; Searle's method.H = KAΔθ/L; in series the same H flows through each layer.
RadiationStefan's law, Wien's law, emissivity, spectral radiancy graph, blackbody.Use kelvin; P ∝ AT⁴; λ_max ∝ 1/T.
Newton's law of coolingState the law; time to cool between two temperatures; cooling curves.Use the average form with the mean temperature of each interval.

Tricks to remember Thermal Properties of Matter

Short memory aids. Say each one aloud once, then use it on a question the same day.

  • 1, 2, 3 for expansion

    α : β : γ = 1 : 2 : 3 for solids.

    Use it when: Converting between linear, area and volume coefficients.

  • Four-degree water

    Water is 'fat' at 4: densest at 4 °C, so the bottom of a frozen lake stays at 4 °C.

    Use it when: Anomalous expansion questions.

  • Conduction like current

    H = Δθ/R with R = L/KA, like I = V/R: series resistances add.

    Use it when: Composite slabs.

  • Stefan four, Wien one

    Power ∝ T⁴ (Stefan); λ_max ∝ 1/T (Wien).

    Use it when: Radiation numericals.

  • Average for cooling

    Newton: drop per minute = K × (average temperature − room temperature).

    Use it when: Cooling-time problems.

Thermal Properties of Matter: exam-level solved questions

Ordered from exam level to HOTS. Cover the solution, write your own, then compare step by step.

Example 1: Maximum density of water · 1 mark · MCQExam level

Water has its maximum density at:
(a) 0 °C
(b) 4 °C
(c) 100 °C
(d) −4 °C

Try it first, then show the solutionSolution
  1. Between 0 °C and 4 °C water contracts on heating (anomalous expansion), so its volume is least and density greatest at 4 °C.

Answer: (b)

Example 2: Why metal feels colder · 1 mark · Assertion-reasonExam level

Assertion: On a cold day, a metal tumbler feels colder to the touch than a wooden one at the same temperature.
Reason: Metal has a much higher thermal conductivity, so it conducts heat away from the hand faster.
(a) Both Assertion and Reason are true, and Reason is the correct explanation for Assertion.
(b) Both Assertion and Reason are true, but Reason is not the correct explanation for Assertion.
(c) Assertion is true and Reason is false.
(d) Assertion is false and Reason is true.

Try it first, then show the solutionSolution
  1. Both are at the same temperature; the sensation of cold is the rate of heat loss from the skin, which is larger for the good conductor.

Answer: (a)

Example 3: Why filament bulbs waste energy · 2 marks · Short answerHarder exam level

The tungsten filament of an old-style bulb runs at about 2900 K. At what wavelength does it radiate most strongly? Use this to explain why such bulbs are inefficient sources of light. (b = 2.9 × 10⁻³ m K) [2]

Try it first, then show the solutionSolution
  1. Visible light lies between about 400 nm and 700 nm, so the peak is in the infrared: most of the energy comes out as heat, not light.

Answer: About 1000 nm (infrared): most of the output is heat, so the bulb is inefficient

Example 4: Comparing radiated power · 3 marks · Short answerHarder exam level

Two spheres of the same material have radii in the ratio 1 : 2 and absolute temperatures in the ratio 2 : 1. Find the ratio of the power they radiate. [3]

Try it first, then show the solutionSolution
  1. P = eσAT⁴ with A = 4πr², so P ∝ r²T⁴
  2. = 4 : 1

Answer: 4 : 1

Example 5: Ice in warm water · 3 marks · Short answerHarder exam level

50 g of ice at 0 °C is added to 200 g of water at 40 °C in a container of negligible heat capacity. Find the final temperature. (L_f = 3.36 × 10⁵ J kg⁻¹, c = 4200 J kg⁻¹ K⁻¹) [3]

Try it first, then show the solutionSolution
  1. Check: heat to melt all the ice = 0.05 × 3.36 × 10⁵ = 16 800 J; heat available from water cooling to 0 °C = 0.2 × 4200 × 40 = 33 600 J, so all the ice melts.
  2. 0.2 × 4200 × (40 − T) = 16 800 + 0.05 × 4200 × T
  3. 33 600 − 840T = 16 800 + 210T, so T = 16 °C

Answer: 16 °C

Example 6: Thermal conductivity and Searle's method · 5 marks · Long answerHarder exam level

(a) Define the coefficient of thermal conductivity and give its SI unit. [1]
(b) Describe Searle's experiment to find the thermal conductivity of a good conductor, explaining the role of lagging and the steady state. [3]
(c) In such an experiment, water flowing at 3.0 g s⁻¹ rises 4 K; the bar has a radius of 2.5 cm and its thermometers 8 cm apart differ by 12 K. Find K. (c of water = 4200 J kg⁻¹ K⁻¹) [1]

Try it first, then show the solutionSolution
  1. (a) K is the heat flowing per second through unit area of a material per unit temperature gradient in the steady state; unit W m⁻¹ K⁻¹.
  2. (b) A lagged thick bar is heated by steam at one end and cooled by water flowing through a coil at the other; two thermometers along the bar read θ₁, θ₂; two read the water's inlet and outlet temperatures θ₃, θ₄.
  3. Lagging prevents sideways heat loss so heat flows along the bar; readings are taken when all four thermometers are steady (steady state), when no heat is stored in the bar.
  4. Heat balance: KA(θ₁ − θ₂)/d = mc(θ₄ − θ₃)/t gives K.
  5. (c) Heat carried away = 0.003 × 4200 × 4 = 50.4 W; K = 50.4 × 0.08/(π × 0.025² × 12) = 171 W m⁻¹ K⁻¹

Answer: (c) About 171 W m⁻¹ K⁻¹

Example 7: A pan of soup left to cool · 3 marks · Short answerHOTS / competency

A pan of soup cools from 90 °C to 70 °C in 8 minutes in a kitchen at 30 °C. Using Newton's law of cooling, find its temperature after a further 8 minutes. [3]

Try it first, then show the solutionSolution
  1. First interval (average 80 °C): 20/8 = K(80 − 30), so K = 0.05 per minute.
  2. Second interval, ending at T (average (70 + T)/2): , so 70 − T = 2 + 0.2T.
  3. 1.2T = 68, so T = 56.7 °C

Answer: About 56.7 °C: it falls only about 13 K in the second 8 minutes, against 20 K in the first

Example 8: A pendulum clock in summer · 3 marks · Short answerHOTS / competency

A pendulum clock with a brass rod (α = 2 × 10⁻⁵ K⁻¹) keeps correct time at 20 °C. How many seconds a day does it lose at 40 °C? [3]

Try it first, then show the solutionSolution
  1. , so
  2. The clock ticks slower; time lost per day = 2 × 10⁻⁴ × 86 400
  3. = 17.3 s

Answer: About 17 seconds a day

Case-study practice (Section D style)

Read the situation, then answer every part. In a school exam set on the board pattern this is a 5-mark question split into 1 + 1 + 2 + 1 marks.

Insulating a house wall

Suppose a brick wall 0.2 m thick (K = 0.6 W m⁻¹ K⁻¹) and 10 m² in area separates a room at 22 °C from the outside at 2 °C. The owner adds a 5 cm layer of foam (K = 0.04 W m⁻¹ K⁻¹) on the outside of the bricks.

  1. (i) · 1 mark

    Find the heat loss through the bare brick wall.

    Answer

    Answer: 600 W

    H = 0.6 × 10 × 20/0.2 = 600 W.

  2. (ii) · 1 mark

    Find the thermal resistance of the brick and of the foam.

    Answer

    Answer: 0.033 K W⁻¹ and 0.125 K W⁻¹

    R = L/KA: 0.2/(0.6 × 10) and 0.05/(0.04 × 10).

  3. (iii) · 2 marks

    Find the heat loss with the foam added.

    Answer

    Answer: About 126 W

    Series: R = 0.158 K W⁻¹; H = 20/0.158 = 126 W, about a fifth of before.

  4. (iv) · 1 mark

    Find the temperature of the brick-foam interface.

    Answer

    Answer: About 17.8 °C

    Drop across brick = 126 × 0.033 = 4.2 K; 22 − 4.2 = 17.8 °C.

Reading the colours of stars

Suppose an astronomer finds that the radiation of star A peaks at 290 nm and that of star B at 580 nm. Treat both as blackbodies. (b = 2.9 × 10⁻³ m K)

  1. (i) · 1 mark

    Find the surface temperature of each star.

    Answer

    Answer: A: 10 000 K; B: 5000 K

    T = b/λ_max.

  2. (ii) · 1 mark

    Which star looks bluish and which yellowish?

    Answer

    Answer: A bluish, B yellowish

    The hotter star's peak is at a shorter wavelength.

  3. (iii) · 1 mark

    Find the ratio of the power emitted per unit area.

    Answer

    Answer: 16 : 1

    I ∝ T⁴ = 2⁴.

  4. (iv) · 2 marks

    If star B has twice the radius of star A, compare their total power.

    Answer

    Answer: A emits 4 times as much

    P ∝ r²T⁴: A/B = (1/2)² × 16 = 4.

Where the marks are

How a typical answer is split into step marks. Show every step: a right final answer alone rarely earns full marks.

The radiation from a star peaks at 400 nm. Find its surface temperature. (b = 2.9 × 10⁻³ m K) (2 marks)

StepMarks
Wien's law: λ_max T = b1
T = 2.9 × 10⁻³/4 × 10⁻⁷ = 7250 K1

20 g of steam at 100 °C is passed into 200 g of water at 25 °C in a copper calorimeter of mass 100 g. Find the final temperature. (c_Cu = 390, c_water = 4200 J kg⁻¹ K⁻¹, L_v = 2.26 × 10⁶ J kg⁻¹; neglect heat losses) (3 marks)

StepMarks
Heat given by steam = condensing + cooling: 0.02 × 2.26 × 10⁶ + 0.02 × 4200 × (100 − T) = 45 200 + 84(100 − T)1
Heat gained by water and calorimeter = (0.2 × 4200 + 0.1 × 390)(T − 25) = 879(T − 25); equate1
45 200 + 8400 − 84T = 879T − 21 975, so 963T = 75 575 and T = 78.5 °C1

Two rods of the same length and area, of conductivities K₁ and K₂, are joined end to end with their free ends at 100 °C and 0 °C. Derive the junction temperature and the equivalent conductivity, and evaluate them for K₁ = 3K₂. (5 marks)

StepMarks
In the steady state the same heat current flows through both rods1
K₁A(100 − θ)/L = K₂A(θ − 0)/L1
θ = 100K₁/(K₁ + K₂) = 75 °C for K₁ = 3K₂1
Series resistances: 2L/(K_eq A) = L/(K₁A) + L/(K₂A), so K_eq = 2K₁K₂/(K₁ + K₂)1
K_eq = 6K₂²/4K₂ = 1.5K₂1

Where students lose marks in Thermal Properties of Matter

The slips examiners see most often, and what to write instead.

  • Mistake: Using °C in gas laws and Stefan's law

    Students substitute 27 and 47 instead of 300 K and 320 K.

    Wrong working

    p₂ = 2.0 × 10⁵ × 47/27.

    Right working

    p₂ = 2.0 × 10⁵ × 320/300 = 2.13 × 10⁵ Pa.

    Do this: Convert to kelvin whenever T appears as a ratio or a power.

    Usually costs: 1-2 marks.

  • Mistake: Assuming all the ice melts

    Students write one equation without checking whether there is enough heat to melt the ice.

    Wrong working

    Large ice mass in a little warm water gives a negative final temperature.

    Right working

    Compare the heat available (cooling water to 0 °C) with mL_f first; if it is less, the final temperature is 0 °C with some ice left.

    Do this: Do the 'enough heat?' check before solving.

    Usually costs: 2 marks.

  • Mistake: Forgetting latent heat in heating problems

    Students apply mcΔT straight from ice to steam.

    Wrong working

    Heat for ice at −10 °C to steam at 100 °C = m × c × 110.

    Right working

    Add the separate stages: warm ice, melt, warm water, boil.

    Do this: Sketch the heating curve and add each segment.

    Usually costs: 2 marks.

  • Mistake: Using the temperature at the start instead of the average in Newton's law of cooling

    The rate changes during the interval, so using the initial excess temperature overestimates it.

    Wrong working

    20/t = K(60 − 20).

    Right working

    20/t = K(50 − 20), using the average 50 °C.

    Do this: Use the mean temperature of each interval.

    Usually costs: 1 mark.

  • Mistake: Explaining anomalous expansion vaguely

    Students say 'water freezes at the top because ice is light' without the 4 °C argument.

    Wrong working

    Lakes freeze from the top because cold air is above.

    Right working

    Water cools and sinks until all of it is at 4 °C (densest). Below 4 °C the cooler water is lighter and stays at the top, where it freezes; ice is a poor conductor, so water below stays at about 4 °C.

    Do this: Mention the density maximum at 4 °C and the insulating ice layer.

    Usually costs: 1-2 marks.

Practice questions on Thermal Properties of Matter

Write each answer on paper first. Open the hint only if you are stuck, and the answer only when you have finished.

  1. Q1 · 1 mark · MCQExam level

    The SI unit of the coefficient of thermal conductivity is:
    (a) W m K⁻¹
    (b) W m⁻¹ K⁻¹
    (c) J m⁻¹ K⁻¹
    (d) W m⁻² K⁻¹

    Hint

    K = HL/(AΔθ).

    Answer

    (b)

  2. Q2 · 1 mark · MCQExam level

    According to the Stefan-Boltzmann law, the energy radiated per second per unit area by a blackbody is proportional to:
    (a) T
    (b) T²
    (c) T³
    (d) T⁴

    Hint

    Fourth power.

    Answer

    (d)

  3. Q3 · 1 mark · Very short answerExam level

    Define specific latent heat of fusion.

    Hint

    Solid to liquid.

    Answer

    The heat needed to change unit mass of a solid at its melting point into liquid at the same temperature.

  4. Q4 · 1 mark · Very short answerExam level

    Why do lakes freeze from the top downward?

    Hint

    Density at 4 °C.

    Answer

    Water is densest at 4 °C; colder water below 4 °C is lighter and stays at the surface, where it freezes first.

  5. Q5 · 2 marks · Short answerExam level

    Convert 50 °C to the Fahrenheit and Kelvin scales.

    Hint

    F = 9C/5 + 32.

    Answer

    122 °F; 323.15 K.

  6. Q6 · 2 marks · Short answerHarder exam level

    A metal rod 1 m long expands by 0.6 mm when heated through 50 K. Find its coefficients of linear and volume expansion.

    Hint

    γ = 3α.

    Answer

    α = 0.6 × 10⁻³/(1 × 50) = 1.2 × 10⁻⁵ K⁻¹; γ = 3.6 × 10⁻⁵ K⁻¹.

  7. Q7 · 2 marks · Short answerHarder exam level

    A steel rod clamped at both ends is heated by 50 K. Find the thermal stress. (Y = 2 × 10¹¹ Pa, α = 1.2 × 10⁻⁵ K⁻¹)

    Hint

    Stress = YαΔT.

    Answer

    2 × 10¹¹ × 1.2 × 10⁻⁵ × 50 = 1.2 × 10⁸ Pa.

  8. Q8 · 2 marks · Short answerHarder exam level

    Show why a burn from 10 g of steam at 100 °C is far worse than one from 10 g of water at 100 °C, if each cools to skin temperature 40 °C on the skin. (L_v = 2.26 × 10⁶ J kg⁻¹)

    Hint

    Steam first condenses.

    Answer

    Water: 0.01 × 4200 × 60 = 2520 J. Steam: 0.01 × 2.26 × 10⁶ + 2520 = 25 120 J, about ten times more.

  9. Q9 · 2 marks · Short answerHarder exam level

    Find the volume of 1 mole of an ideal gas at 0 °C and 1.013 × 10⁵ Pa. (R = 8.31 J mol⁻¹ K⁻¹)

    Hint

    V = nRT/p.

    Answer

    V = 8.31 × 273/1.013 × 10⁵ = 0.0224 m³ (22.4 litres).

  10. Q10 · 3 marks · Short answerHarder exam level

    A wall of area 1 m² is made of a 2 cm layer of wood (K = 0.8 W m⁻¹ K⁻¹) and a 3 cm layer of cork (K = 0.2 W m⁻¹ K⁻¹). The outer faces are at 30 °C (wood side) and 0 °C. Find the heat current and the temperature of the interface.

    Hint

    Thermal resistances R = L/(KA) add in series.

    Answer

    R_wood = 0.02/0.8 = 0.025 K W⁻¹; R_cork = 0.03/0.2 = 0.15 K W⁻¹; H = 30/0.175 = 171 W. Interface: 30 − 171 × 0.025 = 25.7 °C (most of the drop is across the cork).

  11. Q11 · 3 marks · Short answerHarder exam level

    A sphere of radius 5 cm and emissivity 0.8 is at 727 °C. Find the power it radiates. (σ = 5.67 × 10⁻⁸ W m⁻² K⁻⁴)

    Hint

    T = 1000 K; A = 4πr².

    Answer

    P = 0.8 × 5.67 × 10⁻⁸ × 4π(0.05)² × 10¹² = 1.43 × 10³ W.

  12. Q12 · 5 marks · Long answerHarder exam level

    (a) Explain conduction, convection and radiation, giving one everyday example of each. [3]
    (b) Sketch the spectral radiancy of a blackbody at two temperatures and use it to state Wien's displacement law. [2]

    Hint

    Medium needed? Bulk movement?

    Answer

    (a) Conduction: heat passes from particle to particle without bulk movement (a spoon handle in hot tea gets hot). Convection: heated fluid moves, carrying heat (sea breeze; a room heater placed low). Radiation: energy carried by electromagnetic waves, needing no medium (sunlight reaching the Earth). (b) Hump-shaped curves; the hotter one lies higher everywhere with its peak at a shorter wavelength; λ_max T = constant (2.9 × 10⁻³ m K).

  13. Q13 · 3 marks · Short answerHOTS / competency

    A metal sphere cools from 70 °C to 60 °C in 5 minutes and from 60 °C to 52 °C in the next 5 minutes. Using Newton's law of cooling, find the temperature of the surroundings.

    Hint

    Write the average form for both intervals and divide.

    Answer

    10/5 = K(65 − T₀) and 8/5 = K(56 − T₀). Dividing: 1.25 = (65 − T₀)/(56 − T₀), so 70 − 1.25T₀ = 65 − T₀ and T₀ = 20 °C.

Test your recall

Answer in your head or on paper first, then open the card. Pulling an answer out of memory makes it stick far better than re-reading.

  1. 1.Relation between α, β and γ for a solid?Show answer

    β = 2α, γ = 3α.

  2. 2.At what temperature is water densest?Show answer

    4 °C.

  3. 3.Principle of calorimetry?Show answer

    Heat lost by hot bodies = heat gained by cold bodies.

  4. 4.Heat current through a rod?Show answer

    H = KA(θ₁ − θ₂)/L.

  5. 5.What is the steady state?Show answer

    The state in which the temperature at every point stays constant with time.

  6. 6.State Wien's displacement law.Show answer

    λ_max T = constant (≈ 2.9 × 10⁻³ m K).

  7. 7.Stefan's constant?Show answer

    5.67 × 10⁻⁸ W m⁻² K⁻⁴.

  8. 8.State Newton's law of cooling.Show answer

    For small temperature differences, the rate of cooling is proportional to the excess temperature over the surroundings.

Best order to study it

  1. Learn heat and temperature, temperature scales, the ideal gas equation and absolute zero.
  2. Learn linear, area and volume expansion, thermal stress, and expansion of liquids and gases.
  3. Learn the anomalous expansion of water and its effect on lakes.
  4. Practise calorimetry and latent heat, including ice-water problems.
  5. Learn conduction, K, steady state and Searle's experiment; practise composite slabs.
  6. Learn convection, blackbody radiation, Stefan's and Wien's laws, and Newton's law of cooling.

Quick revision checklist

The night before the exam: can you do each of these without looking?

  • Can you convert between °C, °F and K?
  • Can you explain absolute zero from a gas thermometer?
  • Can you find gaps for expansion and thermal stress?
  • Can you explain why lakes freeze from the top?
  • Can you solve a mixture problem with ice melting?
  • Can you describe Searle's experiment and find K?
  • Can you use Stefan's and Wien's laws?
  • Can you solve a Newton's-law-of-cooling problem with the average method?

Thermal Properties of Matter: frequently asked questions

Is Lee's disc method in the ISC Class 11 syllabus?

No. The syllabus says Lee's disc method is not required. You need Searle's experiment for the thermal conductivity of a good conductor.

How much of Stefan's and Wien's laws is needed?

Qualitative ideas of blackbody radiation, the spectral radiancy graph, Wien's displacement law and the Stefan-Boltzmann law with emissivity, plus simple numericals. Deductions from Stefan's law are not necessary.

Why is a cavity with a small hole a good blackbody?

Radiation entering the hole is reflected many times inside and is almost all absorbed before it can escape. The hole therefore absorbs nearly everything, and when heated it emits radiation that depends only on the temperature of the cavity.

Why does temperature stay constant while ice melts?

The heat supplied is used to break the ordered arrangement of molecules (increasing their potential energy), not to increase their average kinetic energy, which is what temperature measures.

Why is the specific heat of water important in daily life?

Its large value means water stores a lot of heat for a small temperature change. Seas keep coastal climates mild, water is an effective coolant in engines, and hot-water bottles stay warm for a long time.

When does Newton's law of cooling fail?

It holds only when the temperature difference between the body and the surroundings is small. For large differences, radiation losses follow the T⁴ law, and the simple proportionality no longer applies.

Based on: CISCE ISC 2028 Physics syllabus (Classes XI and XII); CISCE Regulations for the ISC Examination Year 2028 (Class XI internal examination)