CBSE Class 12 Chemistry sample paper 2026-27: question 4
From the official CBSE sample question paper for 2026-27, section A, question 4, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q4 · 1 mark · MCQAmines
An organic compound “X” on reaction with chloroform and alcoholic KOH gives foul smelling product.
In which of the following case compound X would be produced:
- (A)Chloromethane is treated with AgCN.
- (B)Nitrobenzene is reduced.
- (C)Benzene diazonium chloride is treated with Cu/KCN
- (D)Aniline reacts with Acetyl chloride.
Source: official sample paper from cbseacademic.nic.in (PDF). See it in the full Sample paper 2026-27.
Hints
Open one hint at a time and try again before the next.
Hint 1
Name the test that gives a foul-smelling isocyanide.
Hint 2
Decide which option produces a primary amine.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
A foul-smelling product with and alcoholic KOH is an isocyanide (carbylamine test). Only primary amines give this test, so X must be a primary amine.
- 1 mark
Reduction of nitrobenzene gives aniline, which is a primary amine. The other options give an isocyanide (A), a nitrile (C) or an amide (D), none of which is a primary amine. So the answer is B.
Answer: Option (B)
Where the marks are
- Recognises the carbylamine test and identifies aniline from reduction of nitrobenzene (1 mark)
Revise the chapter
- Chapter: Amines (notes, formulas, where marks are lost and every past question)
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