CBSE Class 12 Chemistry 2024: question 14
Set in the CBSE Class 12 board exam of 2024, paper 56/5/1, section A, question 14, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q14 · 1 mark · Assertion-reasonCompetency-basedChemical Kinetics
Assertion (A) : The units of rate constant of a zero order reaction and rate of reaction are the same.
Reason (R) : In zero order reaction, the rate of reaction is independent of the concentration of reactants.
- (A)Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
- (B)Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of Assertion (A).
- (C)Assertion (A) is true, but Reason (R) is false.
- (D)Assertion (A) is false, but Reason (R) is true.
Source: official question paper from cbse.gov.in (PDF). See it in the full 2024 board paper, set 56/5/1.
Hints
Open one hint at a time and try again before the next.
Hint 1
Write the rate law for n = 0.
Hint 2
Compare the units of k and of the rate.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
For a zero order reaction, rate , so both have units of mol L s. Assertion is true.
- 1 mark
Because the rate does not depend on concentration, rate equals , which is why their units are the same. Reason is true and explains the assertion. Option (A).
Answer: Option (A) (scheme also accepts B)
Where the marks are
- Both statements true; option A or B accepted (1 mark)
Revise the chapter
- Chapter: Chemical Kinetics (notes, formulas, where marks are lost and every past question)
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