CBSE Class 12 Chemistry 2023: question 16
Set in the CBSE Class 12 board exam of 2023, paper 56/5/1, section A, question 16, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q16 · 1 mark · Assertion-reasonCompetency-basedChemical Kinetics
Assertion (A) : For a zero order reaction the unit of rate constant and rate of reaction are same.
Reason (R) : Rate of reaction for zero order reaction is independent of concentration of reactant.
- (A)Both Assertion (A) and Reason (R) are true and Reason (R) is the correct explanation of the Assertion (A).
- (B)Both Assertion (A) and Reason (R) are true, but Reason (R) is not the correct explanation of the Assertion (A).
- (C)Assertion (A) is true, but Reason (R) is false.
- (D)Assertion (A) is false, but Reason (R) is true.
Source: official question paper from cbse.gov.in (PDF). See it in the full 2023 board paper, set 56/5/1.
Hints
Open one hint at a time and try again before the next.
Hint 1
Write the rate law for a zero order reaction.
Hint 2
Compare the units of k and of rate.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
- 1 mark
For a zero order reaction, rate , so the rate is independent of concentration. Hence k has the same unit as rate, mol L⁻¹ s⁻¹.
Both statements are true and R explains A. Option (B) is also accepted by the scheme.
Answer: (A) (scheme also accepts B)
Where the marks are
- Recognises that both statements are true (1 mark)
Revise the chapter
- Chapter: Chemical Kinetics (notes, formulas, where marks are lost and every past question)
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