CBSE Class 12 Chemistry sample paper 2024-25: question 19
From the official CBSE sample question paper for 2024-25, section B, question 19, for 2 marks. Try it first; the hints and our step-by-step solution are below.
Q19 · 2 marks · Very short answerElectrochemistry
Observe the following cell and answer the questions that follow:
a. Represent the cell shown in the figure. (1)
b. Name the carriers of the current in the salt bridge (½)
c. Write the reaction taking place at the anode. (½)
Figure in the paper: Galvanic cell: two beakers joined by an inverted U-shaped salt bridge. Left beaker contains XCl solution with electrode X; right beaker contains YCl2 solution with electrode Y. Electrodes are connected externally through a galvanometer G. See it in the official paper.
Source: official sample paper from cbseacademic.nic.in (PDF). See it in the full Sample paper 2024-25.
Hints
Open one hint at a time and try again before the next.
Hint 1
In cell notation, the anode (oxidation) is written on the left.
Hint 2
Electrons flow in the wire. What moves inside the salt bridge?
Hint 3
Oxidation means loss of electrons by the metal electrode.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
- 1 mark
(a) Y is oxidised (anode) and X⁺ is reduced (cathode). Writing the anode on the left:
- ½ mark
(b) The current in the salt bridge is carried by ions: the cations and anions of the inert electrolyte in it (e.g. and or from KCl/KNO₃). They migrate to keep both solutions electrically neutral.
- ½ mark
(c) Anode (oxidation):
Answer: (a) Y(s)|Y²⁺(aq)||X⁺(aq)|X(s); (b) ions of the salt-bridge electrolyte; (c) Y(s) → Y²⁺(aq) + 2e⁻
Where the marks are
- Correct cell notation with anode on the left and salt bridge shown as || (1 mark)
- Ions (e.g. K⁺, Cl⁻/NO₃⁻) carry current in the salt bridge (½ mark)
- Anode half-reaction Y → Y²⁺ + 2e⁻ (½ mark)
Revise the chapter
- Chapter: Electrochemistry (notes, formulas, where marks are lost and every past question)
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