CBSE Class 12 Chemistry sample paper 2024-25: question 14
From the official CBSE sample question paper for 2024-25, section A, question 14, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q14 · 1 mark · Assertion-reasonCompetency-basedElectrochemistry
Assertion (A): For strong electrolytes, there is a slow increase in molar conductivity with dilution and can be represented by the equation
Reason (R): The value of the constant 'A' for NaCl, , and in a given solvent and at a given temperature is different.
Select the most appropriate answer from the options given below:
- (A)Both A and R are true and R is the correct explanation of A
- (B)Both A and R are true but R is not the correct explanation of A.
- (C)A is true but R is false.
- (D)A is false but R is true.
Source: official sample paper from cbseacademic.nic.in (PDF). See it in the full Sample paper 2024-25.
Hints
Open one hint at a time and try again before the next.
Hint 1
Check the equation in the assertion carefully.
Hint 2
Which quantity is the limiting molar conductivity?
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
The Debye–Hückel–Onsager equation is . The equation given in A is wrong, so A is false.
- 1 mark
A depends on the type of electrolyte (1:1, 2:1, 2:2), so it differs for NaCl, CaCl and MgSO. R is true. Option (D).
Answer: Option (D)
Where the marks are
- Spots the incorrect equation and confirms R (1 mark)
Revise the chapter
- Chapter: Electrochemistry (notes, formulas, where marks are lost and every past question)
- Topic: Conductivity, Molar Conductivity and Kohlrausch's Law
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