CBSE Class 12 Chemistry 2023: question 25
Set in the CBSE Class 12 board exam of 2023, paper 56/5/1, section B, question 25, for 2 marks. Try it first; the hints and our step-by-step solution are below.
Q25 · 2 marks · Very short answerBiomolecules
Give the reaction of glucose with hydrogen cyanide. Presence of which group is confirmed by this reaction ?
Source: official question paper from cbse.gov.in (PDF). See it in the full 2023 board paper, set 56/5/1.
Hints
Open one hint at a time and try again before the next.
Hint 1
HCN undergoes nucleophilic addition with which type of functional group?
Hint 2
Write the open-chain glucose and add H and CN across the C=O.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
- 1 mark
Glucose adds HCN across its C=O group to form a cyanohydrin:
(glucose cyanohydrin) - 1 mark
This addition reaction confirms the presence of a carbonyl group (>C=O), which in glucose is the aldehydic (–CHO) group.
Answer: Glucose cyanohydrin formed; confirms carbonyl (aldehyde) group
Where the marks are
- Correct equation forming glucose cyanohydrin (1 mark)
- Presence of carbonyl/aldehydic group confirmed (1 mark)
Revise the chapter
- Chapter: Biomolecules (notes, formulas, where marks are lost and every past question)
- Topic: Glucose: Structure and Reactions
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