CBSE Class 12 Chemistry 2026: question 25
Set in the CBSE Class 12 board exam of 2026, paper 56/1/1, section C, question 25, for 3 marks. Try it first; the hints and our step-by-step solution are below.
Q25 · 3 marks · Short answerBiomolecules
Write the reactions of D-Glucose with the following :
(a) HI
(b) water
(c) Conc.
Source: official question paper from cbse.gov.in (PDF). See it in the full 2026 board paper, set 56/1/1.
Hints
Open one hint at a time and try again before the next.
Hint 1
HI is a strong reducing agent; bromine water and nitric acid are oxidising agents.
Hint 2
Bromine water oxidises only the aldehyde group; conc. HNO₃ oxidises the primary alcohol group as well.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
- 1 mark
(a) Prolonged heating with HI reduces glucose to n-hexane, showing that its six C atoms are in a straight chain:
- 1 mark
(b) The mild oxidant bromine water oxidises the –CHO group to give gluconic acid:
- 1 mark
(c) Conc. oxidises both the –CHO and the terminal –CH₂OH groups to –COOH, giving saccharic (glucaric) acid:
Answer: (a) n-hexane; (b) gluconic acid; (c) saccharic acid
Where the marks are
- Reaction with HI giving n-hexane (1 mark)
- Reaction with Br₂ water giving gluconic acid (1 mark)
- Reaction with conc. HNO₃ giving saccharic acid (1 mark)
Revise the chapter
- Chapter: Biomolecules (notes, formulas, where marks are lost and every past question)
- Topic: Glucose: Structure and Reactions
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The question is transcribed from the official paper; figures are described in words. The solution, hints and chapter tag are ours. Spotted an error? Write tosupport@questionbuddy.in.