CBSE Class 12 Chemistry sample paper 2023-24: question 2
From the official CBSE sample question paper for 2023-24, section A, question 2, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q2 · 1 mark · MCQAldehydes, Ketones and Carboxylic Acids
product shown. Identify A and B:
- (A)A = 1-phenylethanal, B = acetophenone
- (B)A = Benzophenone, B = formaldehyde
- (C)A = Benzaldehyde, B = Acetophenone
- (D)A = Benzophenone, B = Acetophenone
Figure in the paper: Product is chalcone: two benzene rings joined by the chain -CH=CH-C(=O)-, i.e. C6H5-CH=CH-CO-C6H5. See it in the official paper.
Source: official sample paper from cbseacademic.nic.in (PDF). See it in the full Sample paper 2023-24.
Hints
Open one hint at a time and try again before the next.
Hint 1
Split the product at the C=C double bond.
Hint 2
One part comes from an aldehyde with no α-H and the other from a methyl ketone.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
Chalcone is formed by crossed aldol condensation.
- 1 mark
(no α-H) reacts with the enolate of ; the aldol then loses water to give chalcone. So A = benzaldehyde and B = acetophenone.
Answer: (C) Benzaldehyde and Acetophenone
Where the marks are
- Identifies a crossed aldol between benzaldehyde and acetophenone (1 mark)
Revise the chapter
- Chapter: Aldehydes, Ketones and Carboxylic Acids (notes, formulas, where marks are lost and every past question)
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