CBSE Class 12 Chemistry 2026: question 21
Set in the CBSE Class 12 board exam of 2026, paper 56/1/1, section B, question 21, for 2 marks. Try it first; the hints and our step-by-step solution are below.
Q21 · 2 marks · Very short answerChemical Kinetics
Following reaction takes place in one step :
How will the rate of above reaction change if the volume of the reaction vessel is decreased to one third of its original volume ? Will there be any change in the order of reaction with the reduced volume ?
Source: official question paper from cbse.gov.in (PDF). See it in the full 2026 board paper, set 56/1/1.
Hints
Open one hint at a time and try again before the next.
Hint 1
For a one-step reaction, the rate law exponents equal the stoichiometric coefficients.
Hint 2
How does concentration change when the volume is reduced to one third?
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
Since the reaction is elementary (one step), the rate law follows the stoichiometry: .
- 1 mark
Reducing the volume to makes each concentration 3 times larger:
.The rate becomes 27 times the original rate.
- 1 mark
The order () depends only on the rate law, not on the volume, so it remains unchanged.
Answer: The rate increases 27 times; the order remains the same (3).
Where the marks are
- Writes rate = k[A]²[B] and shows the concentrations become 3 times, giving rate 27 times (1 mark)
- States that the order of reaction does not change (1 mark)
Revise the chapter
- Chapter: Chemical Kinetics (notes, formulas, where marks are lost and every past question)
- Topic: Integrated Rate Equations and Half-Life
More questions from Chemical Kinetics
- 2026 board paper, set 56/5/1, Q23 · 3 marksAnswer the following.
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