CBSE Class 12 Chemistry sample paper 2026-27: question 6
From the official CBSE sample question paper for 2026-27, section A, question 6, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q6 · 1 mark · MCQCompetency-basedChemical Kinetics
Aavya carries out hydrolysis of acetyl chloride. The reaction is represented by the following equation:
She carries out the reaction with (i) equimolar amounts of acetyl chloride and water (ii) excess of water. The rate law obeyed in the two cases will be:
- (A)(i) First order (ii) Second Order
- (B)(i) First order (ii) First order
- (C)(i) Second order (ii) Second order
- (D)(i) Second order (ii) First order
Source: official sample paper from cbseacademic.nic.in (PDF). See it in the full Sample paper 2026-27.
Hints
Open one hint at a time and try again before the next.
Hint 1
Write the rate law that includes both reactants.
Hint 2
Consider what happens to the concentration of a reactant that is present in huge excess.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
(i) With comparable amounts of both reactants, the rate depends on both: rate . This is second order.
- 1 mark
(ii) With water in large excess, stays practically constant. The rate becomes , a pseudo first order reaction.
Answer: Option (D)
Where the marks are
- Identifies second order for (i) and pseudo first order for (ii) (1 mark)
Revise the chapter
- Chapter: Chemical Kinetics (notes, formulas, where marks are lost and every past question)
More questions from Chemical Kinetics
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