CBSE Class 12 Chemistry sample paper 2023-24: question 13
From the official CBSE sample question paper for 2023-24, section A, question 13, for 1 mark. Try it first; the hints and our step-by-step solution are below.
Q13 · 1 mark · Assertion-reasonCompetency-basedAlcohols, Phenols and Ethers
Given below are two statements labelled as Assertion (A) and Reason (R)
Assertion (A): Alcohols react both as nucleophiles and electrophiles.
Reason (R): The bond between C–O is broken when alcohols react as nucleophiles.
Select the most appropriate answer from the options given below:
- (A)Both A and R are true and R is the correct explanation of A
- (B)Both A and R are true but R is not the correct explanation of A.
- (C)A is true but R is false.
- (D)A is false but R is true.
Source: official sample paper from cbseacademic.nic.in (PDF). See it in the full Sample paper 2023-24.
Hints
Open one hint at a time and try again before the next.
Hint 1
Which bond breaks when the oxygen attacks an electrophile?
Hint 2
The C–O bond breaks when alcohols act as electrophiles.
Step-by-step solution
Each step shows the marks it earns, as an examiner would award them. Checked by an independent re-solve from the question paper.
A is true: alcohols act as nucleophiles (O–H bond breaks) and as electrophiles (C–O bond breaks, after protonation).
- 1 mark
As nucleophiles, it is the O–H bond that breaks, not C–O, so R is false.
Answer: (C)
Where the marks are
- Recognises A true and R false (1 mark)
Revise the chapter
- Chapter: Alcohols, Phenols and Ethers (notes, formulas, where marks are lost and every past question)
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